Optimizing of the lost-on-ignition method for determining the residual content of organic oil compounds in contaminated soils
Keywords:
oil pollution, method of weight loss on ignition, gray forest soils, recultivationAbstract
The method of mass loss on ignition is one of the simple and perspective approaches for determining the quantitative content of oil hydrocarbons in contaminated soils. A significant condition for obtaining correct values is the complete combustion of organic
compounds of oil and oil products contained in the soil. The object of the study was oil-contaminated gray forest soils conditionally reclaimed in a laboratory. The initial oil content was 5%, 8.5%, 10% and 15%. The temperature and time of ignition are the main parameters of the method under consideration. The search for the optimal temperature was carried out by sequential ignition for 4 hours from 200 to 600 °C. For oil-contaminated soil samples the optimal temperature range is from 550 °C to 600 °C, and the ignition time is from 2 to 4 hours.
References
Arinushkina E.V. Rukovodstvo po khimicheskomu analizu pochv [Guidelines for the chemical analysis of soils]. M.: MSU, 1970. 487 p.
Vershinin A.A., Petrov A.M., Zainulgabidinov E.R., Karimullin L.K. Neftyanoe zagryaznenie i soderzhanie mikrobnoi biomassy v razlichnykh tipakh pochv [Oil Pollution and Microbial Biomass in Different Types of Soils] // Vestnik Orenburgskogo gosuniversiteta [Bulletin of the Orenburg state university]. 2018. No 3. P. 114‒119. doi: 10.25198/1814-6457-215-114.
Gerelmaa T. Issledovanie protsessov biodegradatsii vyazkikh neftei Mongolii dlya sozdaniya metodov uvelicheniya nefteotdachi i rekul’tivatsii neftezagryaznennykh pochv [Investigation of the processes of biodegradation of viscous oils in Mongolia for the creation of methods for increasing oil recovery and reclamation of oil-contaminated soils]: Summary or PhD (Cand. of Chem.) Tomsk, 2010. 26 p.
Drugov Ju.S., Rodin A.A. Ekologicheskie analizy pri razlivah nefti i nefteproduktov. Prakticheskoe rukovodstvo [Environmental analysis for oil and oil product spills. A practical guide]. SPb.: Anatolia, 2000. 250 p.
Drugov Ju.S., Rodin A.A. Analiz zagrjaznennoj pochvy i opasnyh othodov [Analysis of contaminated soil and hazardous waste]. SPb.: Binom, 2013. 469 p.
Zavgarodnjaja Ju.A., Stepanova A.A., Trofimov S.Ja., Farhodov Ju.R., Pervakova V.N., Sokolova T.A., Aptikaev R.S. Vliyanie vneseniya glinistykh mineralov, mineral’nykh udobrenii i melioranta na razlozhenie organicheskikh pollyutantov v neftezagryaznennom peske v usloviyakh model’nogo opyta [Effect of combined application of clays, mineral fertilizers and liming on the decomposition of oil products in acid oil-polluted
sand (a model experiment)] // Vestnik Moskovskogo universiteta, Ser. 17. Pochvovedenie [Bulletin of the Moscow state university, ser. 17. Pedology]. 2017. № 1. Р. 39‒46.
Zainulgabidinov E.R., Ignat’ev Yu.A., Petrov A.M., Khabibullin R.E. Vliyanie dlitel’noi inkubatsii na sostav normal’nykh uglevodorodov pri raznykh urovnyakh nachal’nogo soderzhaniya nefti v pochve [Effect of long-term incubation on the composition of normal hydrocarbons at different levels of the initial oil content in the soil] // Vestnik tekhnologicheskogo universiteta [Bulletin of the Technological university]. 2016. Vol. 19, No 10. Р. 56-60.
Zainulgabidinov E.R., Ignat’ev Yu.A., Petrov A.M., Khabibullin R.E. Izmenenie sostava normal’nykh uglevodorodov nefti v zavisimosti ot vlazhnosti i fiziko-khimicheskikh kharakteristik serykh lesnykh pochv [Тhe changes of the composition of normal hydrocarbons of oil, depending on humidity and physico-chemical characteristics of gray forest soils] // Vestnik tekhnologicheskogo universiteta [Bulletin of the Technological university]. 2017. Vol. 20, No 15. Р. 127‒130.
Ignat’ev Yu.A., Zainulgabidinov E.R., Petrov A.M. Izmenenie uglevodorodnogo sostava neftezagryaznennoi dernovo-podzolistoi pochvy v standartizirovannykh usloviyakh inkubatsii [changes of the hydrocarbon composition of oil-contaminated soddy-podzolic soil under standardized incubation conditions] // Vestnik Kazanskogo tekhnologicheskogo universiteta [Bulletin of the Kazan Technological university]. 2014. Vol. 17, No 15. Р. 256‒260.
Ignat’ev Yu.A., Zainulgabidinov E.R., Petrov A.M. Primenenie metoda prokalivaniya dlya opredeleniya allokhtonnykh uglevodorodov nefti v pochvakh [Application of the loss-on-ignition method for determining the content of allochthonous hydrocarbons of oil in soils] // Rossiiskii zhurnal prikladnoi ekologii [Russian journal of applied ecology]. 2018. No 3. P. 34‒37.
Lakin G.F. Biometriya [Biometrics]. M.: Vysshaya shkola, 1990. 352 p.
Lozovoi D.V., Balayan A.E., Saksonov M.N., Stom D.I. Ekspress metod obnaruzheniya nefteproduktov v vodnoi srede [Express method of determination of oil products in an aqueous medium] // Analitika i kontrol’ [Analytics and control]. 2006. Vol. 10, No 2. Р. 137‒143.
PND F 16.1:2:2.2:2.3:3.64‒10. Metodika izmereniya massovoi doli nefteproduktov v probakh pochv, gruntov, donnykh otlozhenii, ilov, osadkov stochnykh vod, otkhodov proizvodstva i potrebleniya gravimetricheskim metodom [Methods for measuring the mass fraction of petroleum products in samples of soils, grounds, bottom sediments, silts, sewage sludge, production, and consumption waste by the gravimetric method].
PND F 16.1:2.2.22‒98. Metodika vypolneniya izmerenij massovoj doli nefteproduktov v mineral’nyh, organogennyh, organo-mineral’nyh pochvah i donnyh otlozheniyah metodom IK-spektrometrii [The technique for measuring the mass fraction of petroleum products in mineral, organogenic, organomineral soils and bottom sediments by IR spectrometry].
PND F 16.1:2.21‒98. Kolichestvennyi khimicheskii analiz pochv i otkhodov. Metodika izmerenii massovoi doli nefteproduktov v probakh pochv i gruntov fluorimetricheskim metodom na analizatore zhidkosti «Flyuorat-02» [Quantitative chemical analysis of soil and waste. Methods for measuring the mass fraction of petroleum products in soil and soil samples by the fluorimetric method on a fluid analyzer «Fluorat-02»].
Temerdashev Z.A., Pavlenko L.F., Korpakova I.G., Ermakova Ya.S., Ekilik V.S. O nekotorykh metodicheskikh aspektakh otsenki neftyanogo zagryazneniya vodnykh ob”ektov s uchetom degradatsii nefteproduktov vo vremeni [Some methodological aspects of oil pollution evaluation of water bodies based on the degradation of petroleum products over time] // Analitika i kontrol’ [Analytics and control]. 2016. Vol. 20, No 3. Р. 225-235. doi: 10.15826/analitika.2016.20.3.006.
Fedorova M.A., Usova S.V., Vershinin V.I. Tochnost’ IK-spektrometricheskikh otsenok summarnogo soderzhaniya uglevodorodov v ikh model’nykh smesyakh pri razlichnykh sposobakh izmereniya obobshchennogo analiticheskogo signala [The accuracy of IR-spectometric estimations for total hydrocarbon concentration of model mixtures with different methods to measure the generalized analytical signal] // Analitika i kontrol’ [Analytics and control]. 2014. Vol. 18, No 1. Р. 91‒98.
Abbasian F., Lockington R., Mallavarapu M., Naidu R. Comprehensive review of aliphatic hydrocarbon biodegradation by bacteria // Applied biochemistry and biotechnology. 2015. Vol. 176. P. 670–699. doi: 10.1007/s12010-015-1603-5.
Boyle J.F. A comparison of two methods for estimating the organic matter content of sediments // Journal of paleolimnology. 2004. Vol. 31. P. 125–127. doi: 10.1023/B:JOPL.0000013354.67645.df.
Konen M.E., Jacobs P.M., Burras C.L., Talaga B.J., Mason J.A. Equation for predicting soil organic carbon using loss-on-ignition for north central US soils // Soil science society of America journal. 2002. Vol. 66. P. 1878-1881. doi: 10.2136/sssaj2002.1878.
Heiri O., Lotter A.F., Lemcke G. Loss on ignition as a method for estimating organic and carbonate content in sediments: reproducibility and comparability of results // Journal of paleolimnology. 2001. Vol. 25. P. 101–110. doi: 10.1023/A:1008119611481.
Rojo F. Degradation of alkanes by bacteria. Minireview // Environmental microbiology. 2009. Vol. 11. P. 2477–2490. doi: 10.1111/j.1462-2920.2009.01948.x.
Touch N., Hibino, Takata H., Yamaji S. Loss on ignition - based indices for evaluating organic matter characteristics of littoral sediments // Pedosphere. 2017. Vol. 27. P. 978–984. doi:10.1016/S1002-0160(17)60487-9.
Wang Z., Fingas M. Study of the effects of weathering on the chemical composition of light crude oil using GC/MS GS/FID // Journal of microcolumn separation. 1995. Vol. 7. P. 617-639. doi: 10.1002/mcs.1220070609.
Wang Q.R., Li Y.C, Wang Y. Optimizing the weight loss-on-ignition methodology to quantify organic and carbonate carbon of sediments from diverse sources // Environmental monitoring and assessment. 2011. Vol. 174. P. 241–257. doi: 10.1007/s10661-010-1454-z.
Wang X., Wang J., Zhang J. Comparison of three method for organic and inorganic carbon in calcareous soils of northwestern China // PLoS One. 2012. Vol. 7, No 8. P. 1‒6. doi:10.1371/journal.pone.0044334.
Weliky K., Suess E., Ungerer C.A., Muller P.J., Fischer K. problems with accurate carbon measurement in marine sediments and particulate matter in seawater: a new approach // Limnology and oceanography. 1983. Vol. 28. P. 1252–1259. doi: 10.4319/lo.1983.28.6.1252.
