Effect of iron and magnetite nanoparticles on the binding of cadmium and lead ions by humic acids
DOI:
https://doi.org/10.24852/2411-7374.2024.1.84.92Keywords:
sorption, lead, cadmium, iron, humic acidsAbstract
The article examines the influence of iron nanoparticles (80±5 nm) and magnetite (width from 50 nm to 80 nm and height from 4 nm to 10 nm) on the adsorption of toxic lead and cadmium ions from nitrate aqueous solutions on humic acids which isolated by alkaline extraction from brown coal from the Tyulgan deposit. Adsorption equilibria of cadmium and lead ions were studied in the concentration range from 0.1 mg/l to 1 mg/l at pH 6.0–6.5 on humic acids, iron and magnetite nanoparticles, as well as on iron nanoparticles in the presence of humic acids in mass ratio of 2:8 and on magnetite nanoparticles in the presence of humic acids at a mass ratio of 8:2, since at such ratios an increase in adsorption capacity is observed. Isotherms were described using the Langmuir, Freundlich, and Dubinin-Radushkevich equations. The kind of isotherms for the binding of cadmium ions on humic acids, iron nanoparticles, and magnetite corresponds to the first type of isotherms according to the IUPAC classification and is accompanied by the formation of a monomolecular layer, as well as during the adsorption of lead ions on humic acids and magnetite. On iron nanoparticles, the sorption isotherm of lead ions corresponds to the second type and assumes polymolecular adsorption. The sorption of cadmium and lead ions on iron and magnetite nanoparticles increases in the presence of humic acids, and the mechanism of physical adsorption changes from monomolecular to polymolecular, accompanied by a stronger adsorbate-adsorbate interaction than the adsorbate-adsorbent interaction. This is probably due to the formation of organomineral complexes, leading to charge redistribution and the formation of active adsorption centers on the surface of the sorbent
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